Energy as witness of multipartite entanglement in spin clusters

We derive energy minima for biseparable states in three- and four-spin systems, with Heisenberg Hamiltonian and s <= 5/2. These provide lower bounds for tripartite and quadripartite entanglement in chains and rings with larger spin number N. We demonstrate that the ground state of an $N$-spin Heisenberg chain is $N$-partite entangled, and compute the energy gap with respect to biseparable states for N <= 8

Detection of entanglement between collective spins

Entanglement between individual spins can be detected by using thermodynamics quantities as entanglement witnesses. This applies to collective spins also, provided that their internal degrees of freedom are frozen, as in the limit of weakly-coupled nanomagnets. Here, we extend such approach to the detection of entanglement between subsystems of a spin cluster, beyond such weak-coupling limit. The resulting inequalities are violated in spin clusters with different geometries, thus allowing the detection of zero- and finite-temperature entanglement. Under relevant and experimentally verifiable conditions, all the required expectation values can be traced back to correlation functions of individual spins, that are now made selectively available by four-dimensional inelastic neutron scattering

Entanglement in finite spin rings with noncollinear Ising interaction

We investigate the entanglement properties of finite spin rings, with noncollinear Ising interaction between nearest neighbours. The orientations of the Ising axes are determined either by the spin position within the ring (model A) or by the direction of the bond (model B). In both cases, the considered spin Hamiltonians have a point group symmetry, rather than a translation invariance, as in spin rings with collinear Ising interaction. The ground state of these models exhibit remarkable entanglement properties, resembling GHZ-like states in the absence of an applied magnetic field (model B). Besides, the application of an homogeneous magnetic field allows to modify qualitatively the character of the ground state entanglement, switching from multipartite to pairwise quantum correlations (both models A and B)